While Arsenal are unchanged from the side that beat Leicester City at the weekend, PSG makes for interesting reading.
No Ousmane Dembele, who has been left behind following a dispute with Luis Enrique, but they are boosted by the return of Gianluigi Donnarumma in goal.
The Italian international has missed the last three games with a thigh injury.
Nuno Mendes starts at left back after recovering from a virus but Euro winner Fabian Ruiz is still missing from the starting XI because of an ankle problem.
Arsenal XI: Raya, Timber, Saliba, Gabriel, Calafiori, Saka, Partey, Rice, Martinelli, Havertz, Trossard.
Subs: Neto, Porter, Gabriel Jesus, Kiwior, Jorginho, Merino, Sterling, Kacurri, Lewis-Skelly, Nwaneri, Robinson, Butler-Oyedeji.
Paris St-Germain XI: Donnarumma, Hakimi, Marquinhos, Pacho, Nuno Mendes, Zaire Emery, Vitinha, Neves, Doue, Lee, Barcola.
Subs: Safonov, Tenas, Fabian, Asensio, Muani, Mayulu, Lucas Beraldo, Skriniar, Zague, Naoufel El Hannach, Mbaye.
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